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Journal Articles

Comparative study of the underpotential deposition of Bi in an aqueous electrolyte and an ionic liquid

Tamura, Kazuhisa

Journal of Physical Chemistry C, 127(46), p.22733 - 22739, 2023/11

https://doi.org/10.1021/acs.jpcc.3c05404
 Times Cited Count：0 Percentile：0(Chemistry, Physical)

The underpotential deposition of Bi on Au(111) electrode in 1 M HClO$$_{4}$$ solution and 1-butyl-3-methylimidazolium tetrafluoroborate was investigated using visible light reflectance measurement and surface X-ray scattering techniques. The electrosorption valency of the UPD reaction of Bi was elucidated and it was found that in both 1 M HClO$$_{4}$$ and 1-butyl-3-methylimidazolium tetrafluoroborate the electrosorption valency was smaller than 3, but the detail process in the UPD reaction was different between in two electrolytes. The difference may be originated from the difference in the solvation status of Bi$$^{3+}$$ rather than the electrical double layer structure.

Journal Articles

An X-ray and neutron scattering study of aqueous MgCl$$_2$$ solution in the gigapascal pressure range

Yamaguchi, Toshio*; Fukuyama, Nami*; Yoshida, Koji*; Katayama, Yoshinori*; Machida, Shinichi*; Hattori, Takanori

Liquids, 3(3), p.288 - 302, 2023/09

https://doi.org/10.3390/liquids3030019

We report the structure of an aqueous 2 mol/kg MgCl$$_2$$ solution at pressures from 0.1 MPa to 4 GPa and temperatures from 300 to 500 K revealed by X-ray and neutron scattering measurements. The scattering data are analyzed by empirical potential structure refinement (EPSR) modeling to derive the pair distribution functions, coordination number distributions, angle distributions, and spatial density functions as a function of pressure and temperature. Mg$$^{2+}$$ forms rigid solvation shells extended to the third shell; the first solvation shell of six-fold octahedral coordination with about six water molecules at 0 GPa transforms into about five water molecules and one Cl$$^-$$ due to the formation of the contact ion pairs in the GPa pressure range. The Cl$$^-$$ solvation shows a substantial pressure dependence; the coordination number of a water oxygen atom around Cl$$^-$$ increases from 8 at 0.1 MPa/300 K to 10 at 4 GPa/500 K. The solvent water transforms the tetrahedral network structure at 0.1 MPa/300 K to a densely packed structure in the GPa pressure range; the number of water oxygen atoms around a central water molecule gradually increases from 4.6 at 0.1 MPa/298 K to 8.4 at 4 GPa/500 K.

Journal Articles

Nature of structural instabilities in superconducting Sr$$_3$$Ir$$_4$$Sn$$_{13}$$

Kaneko, Koji; Cheung, Y. W.*; Hu, Y.*; Imai, Masaki*; Tanioku, Yasuaki*; Kanagawa, Hibiki*; Murakawa, Joichi*; Moriyama, Kodai*; Zhang, W.*; Lai, K. T.*; et al.

JPS Conference Proceedings (Internet), 30, p.011032_1 - 011032_6, 2020/03

https://doi.org/10.7566/JPSCP.30.011032

Journal Articles

Lattice dynamics in FeSe via inelastic X-ray scattering and first-principles calculations

Murai, Naoki; Fukuda, Tatsuo; Nakajima, Masamichi*; Kawamura, Mitsuaki*; Ishikawa, Daisuke*; Tajima, Setsuko*; Baron, A. Q. R.*

Physical Review B, 101(3), p.035126_1 - 035126_6, 2020/01

https://doi.org/10.1103/PhysRevB.101.035126
 Times Cited Count：5 Percentile：32.24(Materials Science, Multidisciplinary)

We report an inelastic X-ray scattering investigation of phonons in FeSe superconductor. Comparing the experimental phonon dispersion with density functional theory (DFT) calculations in the non-magnetic state, we found a significant disagreement between them. A better overall agreement was obtained by allowing for spin-polarization in DFT calculations, despite the absence of magnetic order in FeSe. This calculation gives a realistic approximation, at DFT level, of the disordered paramagnetic state of FeSe, in which strong spin fluctuations are present.

Journal Articles

Magnetic field induced triple-$$q$$ magnetic order in trillium lattice antiferromagnet EuPtSi studied by resonant X-ray scattering

Tabata, Chihiro*; Matsumura, Takeshi*; Nakao, Hironori*; Michimura, Shinji*; Kakihana, Masashi*; Inami, Toshiya*; Kaneko, Koji; Hedo, Masato*; Nakama, Takao*; Onuki, Yoshichika*

Journal of the Physical Society of Japan, 88(9), p.093704_1 - 093704_5, 2019/09

https://doi.org/10.7566/JPSJ.88.093704
 Times Cited Count：34 Percentile：88.41(Physics, Multidisciplinary)

Journal Articles

Evidence of a structural quantum critical point in (Ca$$_x$$Sr$$_{1-x}$$)$$_3$$Rh$$_4$$Sn$$_{13}$$ from a lattice dynamics study

Cheung, Y. W.*; Hu, Y. J.*; Imai, Masaki*; Tanioku, Yasuaki*; Kanagawa, Hibiki*; Murakawa, Joichi*; Moriyama, Kodai*; Zhang, W.*; Lai, K. T.*; Yoshimura, Kazuyoshi*; et al.

Physical Review B, 98(16), p.161103_1 - 161103_5, 2018/10

https://doi.org/10.1103/PhysRevB.98.161103
 Times Cited Count：19 Percentile：66.85(Materials Science, Multidisciplinary)

Journal Articles

Momentum dependence of Mott gap excitations in optimally doped YBa$$_2$$Cu$$_3$$O$$_{7-delta}$$ studied by resonant inelastic X-ray scattering

Ishii, Kenji; Tsutsui, Kenji*; Endo, Yasuo*; Toyama, Takami*; Kuzushita, Kaori; Inami, Toshiya; Owada, Kenji; Maekawa, Sadamichi*; Masui, Takahiko*; Tajima, Setsuko*; et al.

AIP Conference Proceedings 850, p.445 - 446, 2006/09

https://doi.org/10.1063/1.2354776

Mott gap excitations in the optimally doped high-$$T_{c}$$ superconductor YBa$$_2$$Cu$$_3$$O$$_{7-delta}$$ ($$T_{c}$$ = 93 K) have been studied by the resonant inelastic X-ray scattering method. Anisotropic spectra in the $$ab$$-plane are observed in a twin-free crystal. The excitation from the one-dimensional CuO chain is enhanced at 2 eV near the zone boundary of the $$b^{*}$$ direction, while the excitation from the CuO$$_2$$ plane is broad at 1.5-4 eV and almost independent of the momentum transfer. Theoretical calculation based on the one-dimensional and two-dimensional Hubbard model reproduces the observed spectra when different values of the on-site Coulomb energy are assumed. The Mott gap of the CuO chain site is found to be much smaller than that of the CuO$$_2$$ plane site.

Journal Articles

Doping Momentum dependence of charge dynamics in Nd$$_{2-x}$$Ce$$_{x}$$CuO$$_4$$ (x=0, 0.075, and 0.15) studied by Resonant inelastic X-ray scattering

Ishii, Kenji; Tsutsui, Kenji*; Endo, Yasuo*; Toyama, Takami*; Maekawa, Sadamichi*; Hoesch, M.; Kuzushita, Kaori; Inami, Toshiya; Tsubota, Masami; Yamada, Kazuyoshi*; et al.

AIP Conference Proceedings 850, p.403 - 404, 2006/09

https://doi.org/10.1063/1.2354756

We report a resonant inelastic X-ray scattering (RIXS) study of charge excitations in the electron-doped high-$$T_{c}$$ superconductor Nd$$_{1.85}$$Ce$$_{0.15}$$CuO$$_4$$. The intraband and interband excitations across the Fermi energy are separated for the first time by tuning the experimental conditions properly to measure charge excitations at low energy. A dispersion relation with $${mathbf q}$$-dependent width emerges clearly in the intraband excitation, while the intensity of the interband excitation is concentrated around 2 eV near the zone center. The experimental results are consistent with theoretical calculation of the RIXS spectra based on the Hubbard model.

Journal Articles

Electronic excitations in hole-doped La$$_{1-x}$$Sr$$_{x}$$MnO$$_{3}$$ studied by resonant inelastic X-ray scattering

Ishii, Kenji; Inami, Toshiya; Owada, Kenji; Kuzushita, Kaori; Mizuki, Junichiro; Murakami, Yoichi; Ishihara, Sumio*; Endo, Yasuo*; Maekawa, Sadamichi*; Hirota, Kazuma*; et al.

Journal of Physics and Chemistry of Solids, 66(12), p.2157 - 2162, 2005/12

https://doi.org/10.1016/j.jpcs.2005.09.011
 Times Cited Count：0 Percentile：0(Chemistry, Multidisciplinary)

We have studied electronic excitations of hole-doped manganese oxides La$$_{1-x}$$Sr$$_x$$MnO$$_3$$ ($$x=0.2$$ and $$0.4$$) by resonant inelastic X-ray scattering at Mn K absorption edge. We observed in the excitation spectra that the Mott gap of La$$_{0.6}$$Sr$$_{0.4}$$MnO$$_{3}$$ was filled by hole-doping. In La$$_{0.8}$$Sr$$_{0.2}$$MnO$$_{3}$$, which shows a metal-insulator transition, we found that temperature dependence of scattering intensity is different between two scattering vectors. It may reflects a anisotropic electronic structure which originates from the orbital degrees of freedom in manganese oxides.

Journal Articles

Momentum dependence of charge excitations in the electron-doped superconductor Nd$$_{1.85}$$Ce$$_{0.15}$$CuO$$_4$$; A Resonant inelastic X-ray scattering study

Ishii, Kenji; Tsutsui, Kenji*; Endo, Yasuo*; Toyama, Takami*; Maekawa, Sadamichi*; Hoesch, M.; Kuzushita, Kaori; Tsubota, Masami; Inami, Toshiya; Mizuki, Junichiro; et al.

Physical Review Letters, 94(20), p.207003_1 - 207003_4, 2005/05

https://doi.org/10.1103/PhysRevLett.94.207003
 Times Cited Count：72 Percentile：89.18(Physics, Multidisciplinary)

We report a resonant inelastic X-ray scattering (RIXS) study of charge excitations in the electron-doped high-$$T_{c}$$ superconductor Nd$$_{1.85}$$Ce$$_{0.15}$$CuO$$_4$$. The intraband and interband excitations across the Fermi energy are separated for the first time by tuning the experimental conditions properly to measure charge excitations at low energy. A dispersion relation with $${mathbf q}$$-dependent width emerges clearly in the intraband excitation, while the intensity of the interband excitation is concentrated around 2 eV near the zone center. The experimental results are consistent with theoretical calculation of the RIXS spectra based on the Hubbard model.

Journal Articles

Mott gap excitations in twin-free YBa$$_2$$Cu$$_3$$O$$_{7-delta}$$ ($$T_{c}$$ = 93 K) studied by resonant inelastic X-ray scattering

Ishii, Kenji; Tsutsui, Kenji*; Endo, Yasuo*; Toyama, Takami*; Kuzushita, Kaori; Inami, Toshiya; Owada, Kenji; Maekawa, Sadamichi*; Masui, Takahiko*; Tajima, Setsuko*; et al.

Physical Review Letters, 94(18), p.187002_1 - 187002_4, 2005/05

https://doi.org/10.1103/PhysRevLett.94.187002
 Times Cited Count：40 Percentile：80.87(Physics, Multidisciplinary)

Mott gap excitations in the optimally doped high-$$T_{c}$$ superconductor YBa$$_2$$Cu$$_3$$O$$_{7-delta}$$ ($$T_{c}$$ = 93 K) have been studied by the resonant inelastic X-ray scattering method. Anisotropic spectra in the $$ab$$-plane are observed in a twin-free crystal. The excitation from the one-dimensional CuO chain is enhanced at 2 eV near the zone boundary of the $$b^{*}$$ direction, while the excitation from the CuO$$_2$$ plane is broad at 1.5-4 eV and almost independent of the momentum transfer. Theoretical calculation based on the one-dimensional and two-dimensional Hubbard model reproduces the observed spectra when different values of the on-site Coulomb energy are assumed. The Mott gap of the CuO chain site is found to be much smaller than that of the CuO$$_2$$ plane site.

Journal Articles

Resonant inelastic X-ray scattering study of the hole-doped manganites La$$_{1-x}$$Sr$$_x$$MnO$$_3$$ ($$x=0.2$$, $$0.4$$)

Ishii, Kenji; Inami, Toshiya; Owada, Kenji; Kuzushita, Kaori; Mizuki, Junichiro; Murakami, Yoichi; Ishihara, Sumio*; Endo, Yasuo*; Maekawa, Sadamichi*; Hirota, Kazuma*; et al.

Physical Review B, 70(22), p.224437_1 - 224437_6, 2004/12

https://doi.org/10.1103/PhysRevB.70.224437
 Times Cited Count：19 Percentile：64.26(Materials Science, Multidisciplinary)

Electronic excitations in the hole doped manganese oxides (La$$_{1-x}$$Sr$$_x$$MnO$$_3$$, $$x=0.2$$ and $$0.4$$) have been elucidated by using the resonant inelastic X-ray scattering (RIXS) method. A doping effect in the strongly correlated electron systems has been observed for the first time. The scattering spectra show that a salient peak appears in low energies indicating the persistence of the Mott gap. At the same time, the energy gap is partly filled by doping holes and the spectral weight energy shifts toward lower energies. The excitation spectra show little change in the momentum space as is in undoped LaMnO$$_3$$. On the other hand, the scattering intensities in the low energy excitations of $$x=0.2$$ are anisotropic in temperature dependence, which indicates an anisotropy of magnetic interaction and underlying effect of the orbital.

Journal Articles

Anisotropy of resonant inelastic X-ray scattering at the $$K$$ edge of Si; Theoretical analysis

Nishikawa, Yunori; Usuda, Manabu; Igarashi, Junichi*

Journal of the Physical Society of Japan, 73(11), p.3171 - 3176, 2004/11

https://doi.org/10.1143/JPSJ.73.3171
 Times Cited Count：3 Percentile：26.42(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Magnetic resonant X-ray scattering at the Ga $$K$$ edge in UGa$$_3$$; A Band theoretical approach

Usuda, Manabu; Igarashi, Junichi*; Kodama, Akio*

Physical Review B, 69(22), p.224402_1 - 224402_5, 2004/06

https://doi.org/10.1103/PhysRevB.69.224402
 Times Cited Count：20 Percentile：65.71(Materials Science, Multidisciplinary)

Magnetic resonant X-ray scattering (MRXS) at the $$K$$ edge of Ga in an antiferromagnetic phase of UGa$$_3$$ is studied on the basis of a band-structure calculation. We find that a relatively large orbital polarization in the unoccupied states of the Ga $$4p$$ band is induced by the $$5f$$ orbital polarizations at neighboring U atoms through the Ga $$4p$$ and U $$5f$$ hybridization, and thereby leading to the large MRXS intensity.

Journal Articles

Cooperative Jahn-Teller effect on the X-ray diffraction spectra in DyB$$_{2}$$C$$_{2}$$

Nagao, Tatsuya*; Igarashi, Junichi

Physica B; Condensed Matter, 345(1-4), p.70 - 73, 2004/03

https://doi.org/10.1016/j.physb.2003.11.023
 Times Cited Count：1 Percentile：7.1(Physics, Condensed Matter)

To investigate the effect of the lattice distortion on the resonant X-ray scattering (RXS) spectra in DyB$$_{2}$$C$$_{2}$$, we study the crystal electric field Hamiltonian to fit the low-lying level scheme. By using the quasi-quartet ground states of the Hamiltonian, we analyze the cooperative Jahn-Teller effect at absolute zero. We find that a certain type of buckling of sheets of B and C atoms is an energetically favored state. This naturally leads to a canted quadrupole ordering phase consistent with the experiment. We show that the obtained lattice distortion gives rise to large intensities on RXS spectra around the Dy L$$_{III}$$ edge by modulating 5d bands.

Journal Articles

${it ab-initio}$ calculation of magnetic resonant X-ray scattering spectra in NiO

Usuda, Manabu; Takahashi, Manabu*; Igarashi, Junichi

Physical Review B, 69(1), p.014408_1 - 014408_7, 2004/01

https://doi.org/10.1103/PhysRevB.69.014408
 Times Cited Count：11 Percentile：49.46(Materials Science, Multidisciplinary)

We have investigated the magnetic X-ray scattering spectra around the $$K$$ edge of Ni in antiferromagnetic NiO on the basis of an ${it ab-initio}$ calculation. By taking account of orbital polarization through the spin-orbit interaction, we reproduce well the spectra obtained experimentally. We have analyzed the contributions of the resonant dipolar, quadrupolar, and non-resonant scattering processes and clarified the mechanism of the resonant magnetic X-ray scattering.

Journal Articles

Resonant X-ray scattering study on the filled skutterudite PrFe$$_4$$P$$_{12}$$

Ishii, Kenji; Inami, Toshiya; Murakami, Yoichi; Hao, L.*; Iwasa, Kazuaki*; Kogi, Masafumi*; Aoki, Yuji*; Sugawara, Hitoshi*; Sato, Hideyuki*; Imada, Shin*; et al.

Physica B; Condensed Matter, 329-333(1-4), p.467 - 468, 2003/05

https://doi.org/10.1016/S0921-4526(02)02037-9
 Times Cited Count：6 Percentile：35.59(Physics, Condensed Matter)

Resonant x-ray scattering study was carried out to investigate an anomalous ordered state ($$T_A$$ = 6.5 K) in the filled skutterudite PrFe$$_4$$P$$_{12}$$. At the Pr-$$L_{III}$$ absorption edge, we observed resonant features in $$h+k+l$$ = odd reflections, which are forbidden in the $$bcc$$ structure above $$T_A$$. Because these reflections contain the difference of anomalous scattering factor between two Pr atoms in the $$bcc$$ unit cell, and the ordered state is attributed to the ordering of two different electronic states of Pr.

Journal Articles

Resonant X-ray scattering from CeB$$_{6}$$

Igarashi, Junichi; Nagao, Tatsuya*

Journal of the Physical Society of Japan, 71(7), p.1771 - 1779, 2002/07

https://doi.org/10.1143/JPSJ.71.1771
 Times Cited Count：15 Percentile：63.76(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Special purpose computer for X-ray scattering analysis of macromolecule in solution

*; *; *;

Inst. Phys. Conf. Ser., (159), p.703 - 706, 1999/00

no abstracts in English

Journal Articles

Mesoscopic structure of SiC fibers by neutron and X-ray scattering

Suzuya, Kentaro; Furusaka, Michihiro*; Watanabe, Noboru*; *; Okamura, K.*; *; Kamiyama, Tomoaki*; Suzuki, Kenji*

J. Mater. Res., 11(5), p.1169 - 1178, 1996/05

no abstracts in English

29 (Records 1-20 displayed on this page)